Noncovalent functionalization of carbon nanotubes and graphene with tetraphenylporphyrins: stability and optical properties from ab initio calculations

Walter Orellana, Julián D. Correa

Resultado de la investigación: Contribución a una revistaArtículo

14 Citas (Scopus)

Resumen

© 2014, Springer Science+Business Media New York. The stability, electronic, and optical properties of single-walled carbon nanotubes (CNTs) and graphene non-covalently functionalized with free-base tetraphenylporphyrin (TPP) molecules is addressed by density functional theory calculations. We study the TPP physisorption on 42 CNT species, particularly those with chiral indices (n,m), where interaction between TPP and the CNT surface, with binding energies ranging from 1.1 to 1.8 eV, where higher energies can be associated with increasing CNT diameters. We also find that the TPP optical absorptions would not be affected by the CNT diameter or chirality. Results for the TPP physisorption on graphene show a remarkable stability with binding energy of 3.2 eV, inducing a small redshift on the π-stacked TPP absorption bands. The strong graphene–TPP interaction also induces a charge transfer from TPP to graphene, indicating a n-type doping mechanism without compromising the graphene structure.
Idioma originalInglés estadounidense
Páginas (desde-hasta)898-905
Número de páginas8
PublicaciónJournal of Materials Science
Volumen50
DOI
EstadoPublicada - 1 ene 2014

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